Thoosje Quick XP Optimizer is a free program that provides 1-click performance enhancement for Windows XP, including faster startup, faster HD access, faster apps, faster intente, and faster overall system performance. It also offers the option to completely undo whatever intervention that it performed on a system.

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Auslogic Disk Defrag is a freeware disk defragmentation tool that seems to be significantly faster than Microsoft’s defrag.